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Journal Articles

Chemical state analysis of high-temperature molten slag components by using high-energy XAFS

Okamoto, Yoshihiro; Osugi, Takeshi; Akabori, Mitsuo; Kobayashi, Toru; Shiwaku, Hideaki

Journal of Molecular Liquids, 232, p.285 - 289, 2017/04

 Times Cited Count:3 Percentile:12.07(Chemistry, Physical)

High energy XAFS measurement using cerium K-edge was performed to study the chemical state of cerium in high-temperature molten slag (SiO$$_{2}$$-CaO-Fe$$_{2}$$O$$_{3}$$-CeO$$_{2}$$). It was found from the change in the nearest Ce-O distance obtained from EXAFS analysis and the energetic shift of the white line peak observed in XANES analysis that oxidation state of cerium was tetravalent in the molten state and trivalent in solid state. The Debye-Waller factor of the nearest Ce-O pair in solid slag was very large even at room temperature, and the change in its value upon heating and melting was very small. This result suggests that cerium is highly disordered and stable in solid slag.

Journal Articles

Effects of basicity and FeO concentration on the retention of $$^{137}$$Cs and $$^{60}$$Co in slag made from non-metallic radioactive wastes

Nakashima, Mikio; Nakashio, Nobuyuki; Kameo, Yutaka; Fukui, Toshiki*; Isobe, Motoyasu*; Otake, Atsushi*; Wakui, Takuji*; Hirabayashi, Takakuni*

Radiochimica Acta, 91(1), p.45 - 51, 2003/01

 Times Cited Count:2 Percentile:18.9(Chemistry, Inorganic & Nuclear)

no abstracts in English

JAEA Reports

Radiation exposure estimates on production and utilization of recycled items using dismantling waste

Nakamura, Hisashi; Nakashima, Mikio

JAERI-Tech 2002-006, 58 Pages, 2002/03

JAERI-Tech-2002-006.pdf:2.56MB

Radiation exposure was estimated on production and utilization of recycled items using dismantling waste by assuming that their usage are restricted to nuclear facilities. The radiation exposure attributed to production of a steel-plate cast iron waste container, a receptacle for slag, and a drum reinforcement was calculated to be in the range of several $$mu$$Sv to several tens of $$mu$$Sv even in recycling contaminated metal waste of which radioactivity concentration of Co-60 is higher than the clearance level by a factor of two figures. It is also elucidated that casting of a multiple casting waste package meets the standards of dose equivalent rate for the transport of a radioactive package and the weight of the package will be able to kept around 20 tons for the convenience of the handling, in case of disposal of metal waste less than 37MBq/g with the steel-plate cast iron waste container. As the results, from the radiological exposure's point of view, it should be possible to use slightly contaminated metal for recycled items in waste management.

Journal Articles

Melting tests for recycling slightly radioactive metallic wastes arising from decommissioning

Nakamura, Hisashi; Fujiki, Kazuo

Nuclear Technology, 117(2), p.195 - 205, 1997/02

 Times Cited Count:8 Percentile:56.29(Nuclear Science & Technology)

no abstracts in English

Journal Articles

Interfacial friction factor for high-pressure steam/water stratified-wavy flow in horizontal pipe

Nakamura, Hideo; Kukita, Yutaka; *

Journal of Nuclear Science and Technology, 32(9), p.868 - 879, 1995/09

 Times Cited Count:4 Percentile:43.23(Nuclear Science & Technology)

no abstracts in English

Journal Articles

R&D on melting of radioactive metal wastes at JAERI

Nakamura, Hisashi; Kanazawa, Katsuo; Fujiki, Kazuo

The 3rd JSME/ASME Joint Int. Conf. on Nuclear Engineering (ICONE),Vol. 4, 0, p.1785 - 1789, 1995/00

no abstracts in English

Journal Articles

Fundamental research on melting of radioactive metal materials

Nakamura, Hisashi; Kanazawa, Katsuo; Sato, Takayuki; ; Fujiki, Kazuo

Proc., SPECTRUM 94,Nuclear and Hazardous Waste Management Int. Topical Meeting,Vol. 1, 0, p.206 - 210, 1994/00

no abstracts in English

Journal Articles

Radioactive metal melting test at Japan Atomic Energy Research Institute

Nakamura, Hisashi; Fujiki, Kazuo

Technology and Programs for Radioactive Waste Management and Environmental Restoration,Vol. 2, p.1683 - 1686, 1993/00

no abstracts in English

Journal Articles

Establishment of corresponding-state principle in molten fluoroberyllates and silicates and its application

Furukawa, Kazuo;

Trans.JIM, 19(19), p.553 - 561, 1978/00

no abstracts in English

Journal Articles

Molten solt LiF-BeF$$_{2}$$(flibe) system and its applications; molten slag,molten-salt breeden reactor,fusion reactor,etc

Furukawa, Kazuo;

Zairyo Kagaku, 14(6), p.302 - 309, 1977/06

no abstracts in English

Journal Articles

Journal Articles

Molten salt technology supported by scientific theory; -Breeder, acitinoide fast reactor,fusion reactor,molten slag glass and air-ships.-

Furukawa, Kazuo

Kinzoku Butsuri Semina, 2(3), p.177 - 184, 1977/03

no abstracts in English

Journal Articles

Development of structural study of liquid iron and slag,and its relation with the steal-making.

Furukawa, Kazuo

Dai-42-Kai Nishiyama Kinen Gijutsu Koza (Nihon Tekko Kyokai), 42, p.1 - 26, 1976/00

no abstracts in English

13 (Records 1-13 displayed on this page)
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